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(i) Inorganic Polymer Chemistry: Definitions of inorganic polymers. Connectivities. Examples of: totally inorganic polymers; inorganic-organic polymers, organometallic polymers, hybrid organic-inorganic polymers. Phosphazene and polyphosphates. Synthetic methods and medicinal applications. Detailed study of: silicates, structures and charge counting. Zeolites, their structures and uses. Silicones: synthesis, structures and medicinal uses. Structure and application of metal organic frameworks (MOFs). (ii) Chemistry of the p-block elements and compounds. Material covered includes: Covalent bonding- Revision of determining the structure of molecules using Lewis Structures and VSEPR Theory, Valence bond theory, Hybridization and its relationship to structure, Hypervalent compounds, The concept and examples of Hard/Soft and Strong/Weak Lewis Acids and Bases, General Trends among the p-block elements and compounds. The elemental structures of carbon, silicon, nitrogen, phosphorus, oxygen and sulfur, A brief overview of the chemistry and compounds of Group 13- 18. (iii) Introduction to the NMR spectroscopy of p-block compounds.
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